Observation of eliminative cationic polymerization within van der Waals clusters

Observation of eliminative cationic polymerization within van der Waals clusters

Dynamics and photochemistry of neutral van der waals clusters.

This review covers the field of excited electronic-state chemical reactions in small clusters. The clusters emphasized are those comprised of an organic chromophore that is electronically excited to initiate the reaction and of various coreactant molecules ranging from water and ammonia to ethers, amines, aromatics, alkanes, alkenes, and diatomics. The reactions discussed include vibrational re...

Nondestructive mass selection of small van der waals clusters.

Clusters of atoms or molecules have been extensively studied by a variety of spectroscopies because of their unusual properties. Experiments with van der Waals clusters of defined sizes are not easily possible because nozzle beam expansions used in their production yield broad size distributions. Moreover, being weakly bound they readily fragment in the commonly used electron impact-ionization ...

Nonadditivity in van der Waals interactions within multilayers.

Working at the macroscopic continuum level, we investigate effective van der Waals interactions between two layers within a multilayer assembly. By comparing the pair interactions between two layers with effective pair interactions within an assembly we assess the significant consequences of nonadditivity of van der Waals interactions. This allows us to evaluate the best numerical estimate to d...

The van der Waals interaction

The interaction between charged particles via the Coulomb interaction is one of the most important features in physics and is familiar to any student of the subject. The way in which electrons and protons bind to form the hydrogen atom is also well known and is a staple of any quantum mechanics course. However, less familiar is the interaction between such bound systems at separation R, which i...